Fast room temperature lability of aluminosilicate zeolites
نویسندگان
چکیده
منابع مشابه
Room temperature detemplation of zeolites through H2O2-mediated oxidation.
Detemplation of zeolite beta has been successfully achieved at low temperature by controlled oxidation of the template using H2O2 and catalyzed by traces of Fe3+. With this approach, unlike calcination, the pristine structure of the material is well preserved; no extra-framework aluminium is formed.
متن کاملDefining the flexibility window in ordered aluminosilicate zeolites
The flexibility window in zeolites was originally identified using geometric simulation as a hypothetical property of SiO2 systems. The existence of the flexibility window in hypothetical structures may help us to identify those we might be able to synthesize in the future. We have previously found that the flexibility window in silicates is connected to phase transitions under pressure, struct...
متن کاملModeling zeolites with metal-supported two-dimensional aluminosilicate films.
Zeolites are one of the most widely used materials in heterogeneous catalysis. However, the current understanding of the relation between structure and reactivity of these complex and highly porous materials mostly comes from studies employing bulk-sensitive techniques and from theoretical calculations based on educated assumptions about the inner surface within the pores present in the framewo...
متن کاملRoom temperature methoxylation in zeolites: insight into a key step of the methanol-to-hydrocarbons process.
Neutron scattering methods observed complete room temperature conversion of methanol to framework methoxy in a commercial sample of methanol-to-hydrocarbons (MTH) catalyst H-ZSM-5, evidenced by methanol immobility and vibrational spectra matched by ab initio calculations. No methoxylation was observed in a commercial HY sample, attributed to the dealumination involved in high silica HY synthesis.
متن کاملFast, noise-free memory for photon synchronization at room temperature
Future quantum photonic networks require coherent optical memories for synchronizing quantum sources and gates of probabilistic nature. We demonstrate a fast ladder memory (FLAME) mapping the optical field onto the superposition between electronic orbitals of rubidium vapor. Using a ladder-level system of orbital transitions with nearly degenerate frequencies simultaneously enables high bandwid...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Nature Communications
سال: 2019
ISSN: 2041-1723
DOI: 10.1038/s41467-019-12752-y